Any hints on how to prove that the function |αsin(A)+sin(A+B)|−|sin(B)|\lvert\alpha\;\sin(A)+\sin(A+B)\rvert – \lvert\sin(B)\rvert is negative over the half of the total area?

Let us assume $\alpha\in[0,1)$ (the case of $\alpha\in(-1,0]$ is similar). As $\sin B>0$ for $B\in (0,\pi)$, the inequality $f(A,B)<0$ amounts to
$$\alpha\sin A<\sin B-\sin(A+B),\quad -[\sin B+\sin(A+B)]<\alpha\sin A.\quad (\star)$$
Notice that
$\sin A=2\sin\left(\frac{A}{2}\right)\cos\left(\frac{A}{2}\right)$,
$\sin B-\sin(A+B)=-2\sin\left(\frac{A}{2}\right)\cos\left(\frac{A}{2}+B\right)$ and
$\sin B+\sin(A+B)=2\cos\left(\frac{A}{2}\right)\sin\left(\frac{A}{2}+B\right)$.
Substituting in $(\star)$ and cancelling the positive terms
$2\sin\left(\frac{A}{2}\right)$ and $2\cos\left(\frac{A}{2}\right)$, we obtain the equivalent inequalities
$$\alpha\cos\left(\frac{A}{2}\right)<-\cos\left(\frac{A}{2}+B\right), \quad -\sin\left(\frac{A}{2}+B\right)<\alpha\sin\left(\frac{A}{2}\right).\quad (\star\star)$$
In $(\star\star)$, the LHS of the first inequality and the RHS of the second are non-negative. Hence $\frac{A}{2}+B$ - which belongs to $\left(0,\frac{3\pi}{2}\right)$ - must be in the second or the third quadrant; otherwise, the first inequality in $(\star\star)$ does not hold. Let us analyze these cases separately:

• If $\frac{\pi}{2}\leq\frac{A}{2}+B\leq\pi$, then the second inequality in $(\star\star)$ holds automatically (its RHS is always non-negative); and the first one can be written as
  $$\alpha\cos\left(\frac{A}{2}\right)<\cos\left(\pi-\frac{A}{2}-B\right).$$ Applying the strictly decreasing function $\cos^{-1}:[0,1]\rightarrow\left[0,\frac{\pi}{2}\right]$ yields:
  $$\pi-\frac{A}{2}-B<\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right).$$
  This of course implies $\frac{A}{2}+B\geq\frac{\pi}{2}$. But we also need $\frac{A}{2}+B\leq\pi$. Combining these, the bounds for $B$ in terms of $A\in(0,\pi)$ are given by
  $$\pi-\frac{A}{2}-\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right)\leq B\leq\pi-\frac{A}{2}.$$
  The difference of the two bounds is $\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right)$. Consequently, the contribution to the area of
  $\{(A,B)\mid f(A,B)<0\}$ is
  $$\int_{\{(A,B)\mid f(A,B)<0,\, \frac{\pi}{2}\leq\frac{A}{2}+B\leq\pi\}}\mathbf{1}= \int_{0}^\pi\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right){\rm{d}}A.\quad (1)$$
• If $\pi\leq\frac{A}{2}+B\leq\frac{3\pi}{2}$, all terms appearing in $(\star\star)$ are non-negative. We first rewrite these inequalities as
  $$\alpha\cos\left(\frac{A}{2}\right)<\cos\left(\frac{A}{2}+B-\pi\right), \quad \sin\left(\frac{A}{2}+B-\pi\right)<\alpha\sin\left(\frac{A}{2}\right).$$
  Next applying strictly monotonic functions
  $\cos^{-1}:[0,1]\rightarrow\left[0,\frac{\pi}{2}\right]$
  and $\sin^{-1}:[0,1]\rightarrow\left[0,\frac{\pi}{2}\right]$ to them results in:
  $$\frac{A}{2}+B-\pi<\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right),\quad \frac{A}{2}+B-\pi<\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right).$$
  Hence the upper bound
  $$B<\pi+\min\left\{\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right),\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right)\right\}-\frac{A}{2}$$
  which of course implies $\frac{A}{2}+B\leq\frac{3\pi}{2}$. But $\pi\leq\frac{A}{2}+B$ is also required. We therefore arrive at the bounds for $B$ in terms of $A\in(0,\pi)$:
  $$\pi-\frac{A}{2}\leq B\leq \pi+\min\left\{\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right),\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right)\right\}-\frac{A}{2}.$$
  The difference of the bounds is $\min\left\{\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right),\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right)\right\}$. Therefore, the contribution to the area of
  $\{(A,B)\mid f(A,B)<0\}$ is
  $$\int_{\{(A,B)\mid f(A,B)<0,\, \pi\leq\frac{A}{2}+B\leq\frac{3\pi}{2}\}}\mathbf{1}\\ =\int_{0}^\pi\min\left\{\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right),\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right)\right\}{\rm{d}}A.\quad (2)$$

Adding $(1)$ and $(2)$, the area of $\{(A,B)\mid f(A,B)<0\}$ turns out to be
$$\int_{0}^\pi\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right){\rm{d}}A\\+ \int_{0}^\pi\min\left\{\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right),\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right)\right\}{\rm{d}}A.\quad (\star\star\star)$$
So the question is if the quantity above coincides with $\frac{\pi^2}{2}$ for all $\alpha\in [0,1)$. First, we claim that the minimum above is
$\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right)$. Notice that:
$$\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right) \leq\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right)\\ \Leftrightarrow \cos^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right)+\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right)\geq\frac{\pi}{2};$$
and the cosine of the last angle appearing above is
$$\left[\alpha\sin\left(\frac{A}{2}\right)\right]\left[\alpha\cos\left(\frac{A}{2}\right)\right] -\sqrt{1-\alpha^2\sin^2\left(\frac{A}{2}\right)} \sqrt{1-\alpha^2\cos^2\left(\frac{A}{2}\right)};$$
which is negative as
$\alpha\sin\left(\frac{A}{2}\right)<\sqrt{1-\alpha^2\cos^2\left(\frac{A}{2}\right)}$ and
$\alpha\cos\left(\frac{A}{2}\right)<\sqrt{1-\alpha^2\sin^2\left(\frac{A}{2}\right)}$ due to $|\alpha|<1$. We conclude that $(\star\star\star)$ is equal to
$$\int_{0}^\pi\cos^{-1}\left(\alpha\cos\left(\frac{A}{2}\right)\right){\rm{d}}A+ \int_{0}^\pi\sin^{-1}\left(\alpha\sin\left(\frac{A}{2}\right)\right){\rm{d}}A.$$
Call the expression above $h(\alpha)$. The goal is to establish $h(\alpha)=\frac{\pi^2}{2}$ for any $\alpha\in[0,1]$. This is clear when $\alpha=0$, and so it suffices to show $\frac{{\rm{d}}h}{{\rm{d}}\alpha}\equiv 0$. One has
$$\frac{{\rm{d}}h}{{\rm{d}}\alpha}= -\int_0^{\pi}\frac{\cos\left(\frac{A}{2}\right)}{\sqrt{1-\alpha^2\cos^2\left(\frac{A}{2}\right)}}{\rm{d}}A +\int_0^{\pi}\frac{\sin\left(\frac{A}{2}\right)}{\sqrt{1-\alpha^2\sin^2\left(\frac{A}{2}\right)}}{\rm{d}}A;$$
which is clearly zero because the change of variable $A\mapsto\pi-A$ indicates
$$\int_0^{\pi}\frac{\cos\left(\frac{A}{2}\right)}{\sqrt{1-\alpha^2\cos^2\left(\frac{A}{2}\right)}}{\rm{d}}A =\int_0^{\pi}\frac{\sin\left(\frac{A}{2}\right)}{\sqrt{1-\alpha^2\sin^2\left(\frac{A}{2}\right)}}{\rm{d}}A.$$
This concludes the proof.